Thermodynamics

Most Probable Speed

vp=2kBTm=2RTMv_p = \sqrt{\frac{2k_B T}{m}} = \sqrt{\frac{2RT}{M}}

Speed at which Maxwell-Boltzmann distribution peaks.

Variables

vp
Most probable speed
Peak of Maxwell distribution
Allowed values: greater than 0
m/s
kB
Boltzmann constant
1.38×10⁻²³
In SI units: kg·m²/(s²·K)
Allowed values: greater than 0
J/K
T
Temperature
Absolute temperature
Allowed values: greater than 0
K
m
Molecular mass
Mass per molecule
Allowed values: greater than 0
kg
R
Gas constant
8.314
In SI units: kg·m²/(s²·mol·K)
Allowed values: greater than 0
J/(mol·K)
M
Molar mass
Mass per mole
Allowed values: greater than 0
kg/mol

Derivation

Set df/dv = 0 for Maxwell-Boltzmann distribution f(v) ∝ v²e^(-mv²/2kT). v_p < v_mean < v_rms.

Your notes

0/5000

Constants in this formula

kB
1.380 649 × 10⁻²³. Exact by definition.
J/K
R
8.314 462 618…. Exact by definition.
J/(mol·K)

Check value

Round inputs run through this page's calculator, with each constant at its tabulated value. Use it to test your own working or a rearranged form. It is a test case, not a real-world example.

  • R = 8.314 462 618… J/(mol·K) (Gas constant)
  • T = 2 K (Temperature)
  • M = 3 kg/mol (Molar mass)

Result: vp = 3.3295571 m/s

Other thermodynamics formulas with the same quantities

Where this formula is listed

Common questions

What is the Most Probable Speed formula?

Most Probable Speed is written v_p = √((2k_B T)/m) = √(2RT/M). Speed at which Maxwell-Boltzmann distribution peaks. It belongs to Thermodynamics, under Kinetic Theory.

What are the units in v_p = √((2k_B T)/m) = √(2RT/M)?

In SI units, v_p is most probable speed, measured in m/s; k_B is boltzmann constant, measured in kg·m²/(s²·K); T is temperature, measured in K; m is molecular mass, measured in kg; R is gas constant, measured in kg·m²/(s²·mol·K); M is molar mass, measured in kg/mol.

How is the Most Probable Speed formula derived?

Set df/dv = 0 for Maxwell-Boltzmann distribution f(v) ∝ v²e^(-mv²/2kT). v_p < v_mean < v_rms. The result is v_p = √((2k_B T)/m) = √(2RT/M).