Thermodynamics

Root Mean Square Speed

vrms=3kBTm=3RTMv_{rms} = \sqrt{\frac{3k_B T}{m}} = \sqrt{\frac{3RT}{M}}

RMS speed of gas molecules.

Variables

vrms
RMS speed
Root mean square velocity
Allowed values: greater than 0
m/s
kB
Boltzmann constant
1.38×10⁻²³
In SI units: kg·m²/(s²·K)
Allowed values: greater than 0
J/K
T
Temperature
Absolute temperature
Allowed values: greater than 0
K
m
Molecular mass
Mass per molecule
Allowed values: greater than 0
kg
R
Gas constant
8.314
In SI units: kg·m²/(s²·mol·K)
Allowed values: greater than 0
J/(mol·K)
M
Molar mass
Mass per mole
Allowed values: greater than 0
kg/mol

Derivation

From ½m⟨v²⟩ = (3/2)kT: v_rms = √(3kT/m).

Your notes

0/5000

Constants in this formula

kB
1.380 649 × 10⁻²³. Exact by definition.
J/K
R
8.314 462 618…. Exact by definition.
J/(mol·K)

Check value

Round inputs run through this page's calculator, with each constant at its tabulated value. Use it to test your own working or a rearranged form. It is a test case, not a real-world example.

  • R = 8.314 462 618… J/(mol·K) (Gas constant)
  • T = 2 K (Temperature)
  • M = 3 kg/mol (Molar mass)

Result: vrms = 4.0778579 m/s

Other thermodynamics formulas with the same quantities

Where this formula is listed

Common questions

What is the Root Mean Square Speed formula?

Root Mean Square Speed is written v_rms = √((3k_B T)/m) = √(3RT/M). RMS speed of gas molecules. It belongs to Thermodynamics, under Kinetic Theory.

What are the units in v_rms = √((3k_B T)/m) = √(3RT/M)?

In SI units, v_r ms is rms speed, measured in m/s; k_B is boltzmann constant, measured in kg·m²/(s²·K); T is temperature, measured in K; m is molecular mass, measured in kg; R is gas constant, measured in kg·m²/(s²·mol·K); M is molar mass, measured in kg/mol.

How is the Root Mean Square Speed formula derived?

From ½m⟨v²⟩ = (3/2)kT: v_rms = √(3kT/m). The result is v_rms = √((3k_B T)/m) = √(3RT/M).