Thermodynamics

Clausius Inequality

ΔSQT\Delta S \geq \frac{Q}{T}

Entropy change is at least Q/T. Equality holds for reversible processes.

Variables

ΔS
Entropy change
Change in entropy
J/K
Q
Heat transfer
Heat added to system
J
T
Temperature
Temperature of reservoir
K

Derivation

From second law: for irreversible processes, entropy generation > 0, so ΔS > Q/T.

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Common questions

What is the Clausius Inequality formula?

Clausius Inequality is written ΔS ≥Q/T. Entropy change is at least Q/T. Equality holds for reversible processes. It belongs to Thermodynamics, under Second Law.

What are the units in ΔS ≥Q/T?

In SI units, ΔS is entropy change, measured in kg·m²/(s²·K); Q is heat transfer, measured in kg·m²/s²; T is temperature, measured in K.

How is the Clausius Inequality formula derived?

From second law: for irreversible processes, entropy generation > 0, so ΔS > Q/T. The result is ΔS ≥Q/T.