Thermodynamics

Heat Capacity Relation

Mayer relation: C_p is always greater than C_v by R for ideal gases.

Variables

C_p
Heat capacity (constant P)
Molar heat capacity at constant pressure
J/(mol·K)
C_v
Heat capacity (constant V)
Molar heat capacity at constant volume
J/(mol·K)
R
Gas constant
8.314
J/(mol·K)

Derivation

At constant P, heat goes to both internal energy and work: C_p = (∂H/∂T)_p = C_v + R.

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