Thermodynamics

Entropy Change (Ideal Gas)

ΔS=nCVlnTfTi+nRlnVfVi\Delta S = nC_V \ln\frac{T_f}{T_i} + nR\ln\frac{V_f}{V_i}

Entropy change for ideal gas between two states.

Variables

ΔS
Entropy change
Change in entropy
J/K
n
Moles
Amount of gas
mol
C_V
Molar heat capacity
At constant volume
J/(mol·K)
T_f
Final temperature
Final temp
K
T_i
Initial temperature
Initial temp
K
R
Gas constant
8.314
J/(mol·K)
V_f
Final volume
Final volume
V_i
Initial volume
Initial volume

Derivation

dS = dQ/T = (nC_V dT + PdV)/T, integrate.

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Common questions

What is the Entropy Change (Ideal Gas) formula?

Entropy Change (Ideal Gas) is written ΔS = nCᵥ lnT_f/Tᵢ + nRlnV_f/Vᵢ. Entropy change for ideal gas between two states. It belongs to Thermodynamics, under Entropy.

What are the units in ΔS = nCᵥ lnT_f/Tᵢ + nRlnV_f/Vᵢ?

In SI units, ΔS is entropy change, measured in kg·m²/(s²·K); n is moles, measured in mol; C_V is molar heat capacity, measured in kg·m²/(s²·mol·K); T_f is final temperature, measured in K; T_i is initial temperature, measured in K; R is gas constant, measured in kg·m²/(s²·mol·K); V_f is final volume, measured in m³; V_i is initial volume, measured in m³.

How is the Entropy Change (Ideal Gas) formula derived?

dS = dQ/T = (nC_V dT + PdV)/T, integrate. The result is ΔS = nCᵥ lnT_f/Tᵢ + nRlnV_f/Vᵢ.